スギウラ マサハル   Sugiura Masaharu
  杉浦 正晴
   所属   崇城大学  薬学部 薬学科
   崇城大学大学院  薬学研究科 薬学専攻
   職種   教授
言語種別 英語
発行・発表の年月 1998/06
形態種別 原著論文
査読 査読有り
標題 Chiral dienolate-based remote asymmetric induction: The asymmetric α- oxylation/Pd(0)-catalyzed allylic substitution sequence leading to γ-chiral α,β-unsaturated acid derivatives
執筆形態 共著
掲載誌名 Tetrahedron Letters
掲載区分国外
巻・号・頁 39,pp.4351-4354
著者・共著者 Masaharu Sugiura, Yasuhiro Yagi, Shih Yi Wei, Takeshi Nakai
概要 The asymmetric α-oxylation of the dienolates derived from chiral α,β- or β,γ-unsaturated imide with dibenzyl peroxydicarbonate followed by the Pd(0) catalyzed reactions of the resulting allylic carbonate with various nucleophiles (alkylation, etherification, and amination) is shown to provide the γ-(S)- or -(R) configurated α,β-unsaturated imide, respectively, with a high level of stereocontrol.
DOI 10.1016/S0040-4039(98)00770-9
ISSN 00404039
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