スギウラ マサハル   Sugiura Masaharu
  杉浦 正晴
   所属   崇城大学  薬学部 薬学科
   崇城大学大学院  薬学研究科 薬学専攻
   職種   教授
言語種別 英語
発行・発表の年月 2003/06
形態種別 原著論文
査読 査読有り
標題 Chiral Sulfoxides as Neutral Coordinate-Organocatalysts in Asymmetric Allylation of N-Acylhydrazones Using Allyltrichlorosilanes
執筆形態 共著
掲載誌名 J. Am. Chem. Soc.
掲載区分国外
巻・号・頁 125,pp.6610-6610
著者・共著者 S. Kobayashi, C. Ogawa, H. Konishi, M. Sugiura
概要 Sulfoxides were first introduced to the allylation of N-acylhydrazones with allyltrichlorosilanes as effective neutral coordinate-organocatalysts (NCOs). Both high diastereo- and enantioselectivity were attained when optically active chiral sulfoxides were used. Asymmetric crotylations using (Z)- and (E)-crotyltrichlorosilanes showed a high level of stereospecificity (Z → anti and E → syn) with high enantioselectivity. Copyright © 2003 American Chemical Society.
DOI 10.1021/ja035061m
ISSN 00027863
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