スギウラ マサハル   Sugiura Masaharu
  杉浦 正晴
   所属   崇城大学  薬学部 薬学科
   崇城大学大学院  薬学研究科 薬学専攻
   職種   教授
言語種別 英語
発行・発表の年月 2013/04
形態種別 原著論文
標題 Facile Synthesis of Chiral 1,2-Chlorohydrins via the Ring-opening of meso-Epoxides Catalyzed by Chiral Phosphine Oxides
執筆形態 共著
掲載誌名 Tetrahedron
掲載区分国外
巻・号・頁 69,pp.3075-3081
著者・共著者 Kotani, S.; Furusho, H.; Sugiura, M. Nakajima, M.
概要 The facile synthesis of chiral 1,2-chlorohydrins via the enantioselective ring-opening of meso-epoxides with silicon tetrachloride in the presence of a chiral phosphine oxide was accomplished. The chiral 1,2-chlorohydrins were also obtained from the corresponding cis-alkenes in one-pot without significant loss in the selectivity, thereby permitting easy access to the 1,2-chlorohydrins from cis-alkenes with good yields and enantioselectivities. © 2013 Elsevier Ltd. All rights reserved.
DOI 10.1016/j.tet.2013.01.066
ISSN 00404020
PermalinkURL https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84874659628&origin=inward