スギウラ マサハル   Sugiura Masaharu
  杉浦 正晴
   所属   崇城大学  薬学部 薬学科
   崇城大学大学院  薬学研究科 薬学専攻
   職種   教授
言語種別 英語
発行・発表の年月 2009/08
形態種別 原著論文
査読 査読有り
標題 Novel enantioselective direct aldol-type reaction promoted by a chiral phosphine oxide as an organocatalyst
執筆形態 共著
掲載誌名 Tetrahedron Letters
掲載区分国外
巻・号・頁 50,pp.4602-4605
著者・共著者 Shunsuke Kotani, Yasushi Shimoda, Masaharu Sugiura, Makoto Nakajima
概要 Chiral phosphine oxide successfully catalyzed the direct aldol-type reactions of cyclohexanone derivatives and benzaldehyde derivatives in high stereoselectivities. The reaction mechanism involves the in situ formation of trichlorosilyl enol ethers. The present reaction could be extended to the cross-aldol reactions between two aldehydes. © 2009 Elsevier Ltd. All rights reserved.
DOI 10.1016/j.tetlet.2009.05.065
ISSN 00404039
PermalinkURL https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=67449088256&origin=inward