スギウラ マサハル   Sugiura Masaharu
  杉浦 正晴
   所属   崇城大学  薬学部 薬学科
   崇城大学大学院  薬学研究科 薬学専攻
   職種   教授
言語種別 英語
発行・発表の年月 2008/06
形態種別 原著論文
査読 査読有り
標題 First Asymmetric Abramov-type Phosphonylation of Aldehydes with Trialkyl Phosphites Catalyzed by Chiral Lewis Bases
執筆形態 共著
掲載誌名 Tetrahedron
掲載区分国外
巻・号・頁 64,pp.6415-6419
著者・共著者 Kyoko Nakanishi, Shunsuke Kotani, Masaharu Sugiura, Makoto Nakajima
概要 Chiral phosphine oxides (Lewis bases) catalyze silicon tetrachloride-mediated, enantioselective phosphonylation of aldehydes with trialkyl phosphites (Abramov-type reaction), which leads to optically active α-hydroxyphosphonates with moderate enantioselectivities. 31P NMR analysis of the phosphonylation of benzaldehyde with triethyl phosphite supports the assumed reaction mechanism. © 2008 Elsevier Ltd. All rights reserved.
DOI 10.1016/j.tet.2008.04.078
ISSN 00404020
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