スギウラ マサハル   Sugiura Masaharu
  杉浦 正晴
   所属   崇城大学  薬学部 薬学科
   崇城大学大学院  薬学研究科 薬学専攻
   職種   教授
言語種別 英語
発行・発表の年月 2005/08
形態種別 総説
査読 査読有り
標題 N-Acylhydrazones as Versatile Electrophiles for the Synthesis of Nitrogen-containing Compounds
執筆形態 共著
掲載誌名 Angew. Chem. Int. Ed.
掲載区分国外
巻・号・頁 44,pp.5176-5186
著者・共著者 M. Sugiura, S. Kobayashi
概要 (Chemical Equation Presented) The use of N-acylhydrazones as electrophiles in reactions with nucleophiles has recently made some important advances. N-Acylhydrazones, which can be readily prepared and stored, act as stable imine surrogates in these reactions. The hydrazide products are useful, often chiral building blocks which can be transformed into various nitrogen-containing compounds by cleavage of the N-N bond. The N-acyl groups often play important roles as templates for metal catalysis in controlling stereochemistry. This Minireview summarizes the most recent results of N-acylhydrazone chemistry, and provides an overview of current developments in this field. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
DOI 10.1002/anie.200500691
ISSN 14337851
PMID 16059954
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